Browsing Articles by Subject "Carbenes (Methylene compounds)"

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1,3-Bis(2,6-diisopropylphenyl)-2-trichloromethylimidazolidine

Stack, Darcie L.; Masuda, Jason Douglas, 1977- (MDPI, 2017-10-12)

A new chloroform adduct of the N-heterocyclic carbene (NHC) 1,3-bis(2,6-diisopropylphenyl)imidazolidin-2-ylidene (SIPr) has been prepared via C–H bond activation of the chloroform at the carbene carbon. This redox ...
Anhydrous TEMPO-H: reactions of a good hydrogen atom donor with low-valent carbon centres

Giffin, Nick A.; Makramalla, Miller; Hendsbee, Arthur D.; Robertson, Katherine N.; Sherren, Cody; Pye, Cory C.; Masuda, Jason Douglas, 1977-; Clyburne, Jason A. C. (Royal Society of Chemistry, 2011)

In this paper, we report a novel synthesis of anhydrous 1-hydroxy-2,2,6,6-tetramethyl-piperidine (TEMPO-H). An X-ray crystal structure and full characterization of the compound are included. Compared to hydrated TEMPO-H, ...
Crystal structure of 2-chloro-1,3-(2,6-diisopropylphenyl)- 4,5-dihydro-1H-imidazol-3-ium tetrakis- (3,5-trifluoromethylphenyl)borate

Stack, Darcie L.; Masuda, Jason Douglas, 1977- (International Union of Crystallography, 2016-10)

The title compound, C [subscript 27] H[subscript 38]ClN[subscript 2] [superscript +][centre dot]C[subscript 32]H[subscript 12]BF[subscript 24][superscript -], was synthesized by reacting the product formed from a previous ...

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