([eta superscript 5]-Cyclopentadienyl)[(1,2,3,4,4a,10a-[eta])-1-methylthianthrene]iron(II) hexafluoridophosphate acetone 0.33-solvate

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dc.creator Hendsbee, Arthur D.
dc.creator Masuda, Jason Douglas, 1977-
dc.creator Piorko, Adam
dc.date.accessioned 2013-06-14T15:07:39Z
dc.date.available 2013-06-14T15:07:39Z
dc.date.issued 2009-11
dc.identifier.issn 0108-2701
dc.identifier.uri http://library2.smu.ca/xmlui/handle/01/24997
dc.description Publisher's version/PDF
dc.description.abstract The title complex salt, [Fe(C[subscript 5]H[subscript 5])(C[subscript 13]H[subscript 10]S[subscript 2])]PF[subscript 6][middle dot]0.33C[subscript 3]H[subscript 6]O, obtained from an acetone–diethyl ether–dichloromethane mixture at 280 (2) K, has three cationic molecules (A–C), three hexafluoridophosphate counter-anions and one acetone solvent molecule in the asymmetric unit. Two of the three cations contain FeCp (Cp is cyclopentadienyl) inside the fold of the heterocycle. The dihedral angles between the planes of the external (complexed and uncomplexed) benzene rings in the thianthrene molecule are 146.5 (2)° for FeCp-out-of-fold molecule A, and 139.0 (3) and 142.5 (2)° for the two FeCp-infold molecules B and C, respectively. The complexed Cp and benzene rings in each molecule are almost parallel, with a dihedral angle between the planes of 0.2 (5)° for molecule A, 2.8 (5)° for B, and 2.19 (4) and 6.86 (6)° for the disordered Cp ring in C.
dc.language.iso en en_CA
dc.relation.uri http://dx.doi.org/10.1107/S0108270109035847
dc.subject.lcsh Salts
dc.subject.lcsh Crystallography
dc.subject.lcsh Organometallic compounds
dc.subject.lcsh Heterocyclic compounds
dc.title ([eta superscript 5]-Cyclopentadienyl)[(1,2,3,4,4a,10a-[eta])-1-methylthianthrene]iron(II) hexafluoridophosphate acetone 0.33-solvate en_CA
dc.type Text en_CA
dcterms.bibliographicCitation Acta Crystallographica C65, m466-m468. (2009)

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