dc.creator |
Hendsbee, Arthur D. |
|
dc.creator |
Masuda, Jason Douglas, 1977- |
|
dc.creator |
Piorko, Adam |
|
dc.date.accessioned |
2013-06-17T15:00:00Z |
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dc.date.available |
2013-06-17T15:00:00Z |
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dc.date.issued |
2011-11 |
|
dc.identifier.issn |
0108-2701 |
|
dc.identifier.uri |
http://library2.smu.ca/xmlui/handle/01/25000 |
|
dc.description |
Publisher's version/PDF |
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dc.description.abstract |
In the structure of the title complex salt, [Fe(C[subscript 5]H[subscript 5])(C[subscript 12]H[subscript 8]O[subscript 3]S)]PF[subscript 6], the coordinated cyclopentadienyl (Cp) and benzene ring planes are almost parallel, with a hinge angle between the planes of 0.8 (2)°. The hinge angle between the planes of the peripheral (coordinated and uncoordinated) benzene rings in the coordinated phenoxathiin 10,10-dioxide molecule is 169.9 (2)°, and the FeCp moiety is located inside the shallow fold of the heterocycle. The hinge angle between the benzene ring planes in the free heterocycle, C[subscript 12]H[subscript 8]O[subscript 3]S, is 171.49 (6)°. |
|
dc.description.provenance |
Submitted by Trish Grelot (trish.grelot@smu.ca) on 2013-06-17T15:00:00Z
No. of bitstreams: 1
piorko_adam_article_2011_p.pdf: 196345 bytes, checksum: ffb278656ce8c27afb287aab52361b9d (MD5) |
en |
dc.description.provenance |
Made available in DSpace on 2013-06-17T15:00:00Z (GMT). No. of bitstreams: 1
piorko_adam_article_2011_p.pdf: 196345 bytes, checksum: ffb278656ce8c27afb287aab52361b9d (MD5)
Previous issue date: 2011 |
en |
dc.language.iso |
en |
en_CA |
dc.publisher |
International Union of Crystallography |
|
dc.relation.uri |
http://dx.doi.org/10.1107/S0108270111042715 |
|
dc.subject.lcsh |
Benzene |
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dc.subject.lcsh |
Organometallic compounds |
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dc.subject.lcsh |
Heterocyclic compounds |
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dc.subject.lcsh |
Aromatic compounds |
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dc.subject.lcsh |
Oxidation |
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dc.title |
([eta superscript 5]-Cyclopentadienyl)([eta superscript 6]-phenoxathiin 10,10-dioxide)iron(II) hexafluoridophosphate and phenoxathiin 10,10-dioxide |
en_CA |
dc.type |
Text |
en_CA |
dcterms.bibliographicCitation |
Acta Crystallographica C67, m351-m354. ( 2011) |
|