Surface films : do they influence the effectiveness of oil spill chemical dispersants as studied in a wave tank facility?

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dc.contributor.advisor Clyburne, Jason A. C. (Jason Alexander Cameron), 1968-
dc.creator King, Thomas L.
dc.date.accessioned 2013-09-17T18:46:29Z
dc.date.available 2013-09-17T18:46:29Z
dc.date.issued 2011
dc.identifier.other TD427 P4 K575 2011
dc.identifier.uri http://library2.smu.ca/xmlui/handle/01/25195
dc.description 97 leaves : ill. ; 29 cm.
dc.description Includes abstract and appendices.
dc.description Includes bibliographical references (leaves 71-74).
dc.description.abstract Lab basins and wave tanks have unnatural boundaries (walls) that provide an ideal environment for surface film formation on seawater. Surface films form from natural surfactants in oil and dispersant overspray when applied to seawater. The adsorption process of selected crude oils, Arabian Light (ALC) and Alaskan North Slope (ANS) on static seawater in a lab basin was demonstrated to follow diffusion-controlled short time limit adsorption kinetics. The process of crude oil spreading on the surface of the basin seawater was affected in the presence of surface films as shown using kinetic models. ANS dispersed in the dynamic wave tank seawater with and without a surface film (dispersant overspray) was evaluated using kinetic models. It was found that oil dispersed in wave tank seawater, in the presence of dispersant overspray, influences oil dispersant effectiveness and produced confounding outcomes that are an unnatural model of dispersed oil fate and effects. en_CA
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dc.description.provenance Made available in DSpace on 2013-09-17T18:46:29Z (GMT). No. of bitstreams: 1 king_thomas_l_masters_2011.PDF: 3842369 bytes, checksum: 34f1a0e7d7d141393f915400f8b6b542 (MD5) en
dc.language.iso en en_CA
dc.publisher Halifax, N.S. : Saint Mary's University
dc.subject.lcc TD427.P4
dc.subject.lcsh Surface chemistry
dc.subject.lcsh Dispersing agents
dc.subject.lcsh Oil pollution of water
dc.title Surface films : do they influence the effectiveness of oil spill chemical dispersants as studied in a wave tank facility? en_CA
dc.type Text en_CA
thesis.degree.name Master of Science in Applied Science
thesis.degree.level Masters
thesis.degree.discipline Chemistry
thesis.degree.grantor Saint Mary's University (Halifax, N.S.)
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