dc.creator |
Todd, Angela D. K. |
|
dc.creator |
McClennan, William L. |
|
dc.creator |
Masuda, Jason Douglas, 1977- |
|
dc.date.accessioned |
2018-02-06T13:47:11Z |
|
dc.date.available |
2018-02-06T13:47:11Z |
|
dc.date.issued |
2016 |
|
dc.identifier.uri |
http://library2.smu.ca/handle/01/27267 |
|
dc.description |
Publisher's Version/PDF |
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dc.description.abstract |
The reaction of trimethylaluminum with the bis-N,N[prime] -(2,6-diisopropylphenyl)imidazolin-2-imine (L–H) ligand 1 afforded several new organometallic aluminium complexes. Reaction in a 1 : 1 stoichiometry at room temperature afforded a Lewis acid–base adduct, whereas thermolysis resulted in the loss of methane and the formation of a dimer complex, (L-AlMe[subscript 2])[subscript 2]. 3. When reacted in a 1 : 2 ratio at 110 [degreesl]C, the loss of two equivalents of methane yielded L[subscript 2]AlMe, 5, whereas when the reaction was performed at 60 [degrees]C, (L–H)AlMe[subscript 2](L), 4, was found as an intermediate in the reaction. Compound 2 is, to the best of our knowledge, the first example of a structurally characterized primary imine coordinated to a triorganoaluminum(III) center. Attempts to form a two coordinate aluminum cation by CH[subscript 3][superscript -] abstraction are documented. All products were characterized via normal spectroscopic techniques and single crystal X-ray diffraction. |
en_CA |
dc.description.provenance |
Submitted by Betty McEachern (betty.mceachern@smu.ca) on 2018-02-06T13:47:11Z
No. of bitstreams: 1
Masuda_Jason_D_article_2016a.pdf: 696800 bytes, checksum: d19407cc9097d98bcae3e6b262d53af0 (MD5) |
en |
dc.description.provenance |
Made available in DSpace on 2018-02-06T13:47:11Z (GMT). No. of bitstreams: 1
Masuda_Jason_D_article_2016a.pdf: 696800 bytes, checksum: d19407cc9097d98bcae3e6b262d53af0 (MD5)
Previous issue date: 2016 |
en |
dc.language.iso |
en |
en_CA |
dc.publisher |
Royal Society of Chemistry |
en_CA |
dc.rights |
Creative Commons Attribution License or Creative Commons Attribution Non-Commercial License |
|
dc.subject.lcsh |
Organoaluminum compounds |
|
dc.subject.lcsh |
Imidazolines |
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dc.subject.lcsh |
Ligands |
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dc.title |
Organoaluminum(III) complexes of the bis-N,N[prime]-(2,6-diisopropylphenyl)imidazolin-2-imine ligand |
en_CA |
dc.type |
Text |
en_CA |
dcterms.bibliographicCitation |
RSC Advances 6(73), 69270-69276. (2016) |
en_CA |