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([eta superscript 5]-Cyclopentadienyl)[(1,2,3,4,4a,10a-[eta])-1-methylthianthrene]iron(II) hexafluoridophosphate acetone 0.33-solvate

Hendsbee, Arthur D.; Masuda, Jason Douglas, 1977-; Piorko, Adam (2009-11)
([eta superscript 5]-Cyclopentadienyl)[(1,2,3,4,4a,12a-[eta])-naphtho[2,3-b][1,4]benzodioxine]iron(II) hexafluoridophosphate

Hendsbee, Arthur D.; Masuda, Jason Douglas, 1977-; Piorko, Adam (International Union of Crystallography, 2010-09)
Anhydrous TEMPO-H: reactions of a good hydrogen atom donor with low-valent carbon centres

Giffin, Nick A.; Makramalla, Miller; Hendsbee, Arthur D.; Robertson, Katherine N.; Sherren, Cody; Pye, Cory C.; Masuda, Jason Douglas, 1977-; Clyburne, Jason A. C. (Royal Society of Chemistry, 2011)
([eta superscript 5]-Cyclopentadienyl)[(1,2,3,4,4a,12a-[eta])-naphtho[2,3-b][1,4]benzodioxine]iron(II) hexafluoridophosphate

Masuda, Jason Douglas, 1977-; Piorko, Adam; Hendsbee, Arthur D. (International Union of Crystallography, 2010-09)
1-(2,4,6-Triisopropylphenyl)ethanone

Blair, Amber D.; Hendsbee, Arthur D.; Masuda, Jason Douglas, 1977- (Wiley-Blackwell, 2011-10)
Crystal structure of 2-chloro-1,3-bis(2,6-diiso- propylphenyl)-1,3,2-diazaphospholidine 2-oxide

Veinot, Alex J.; Hendsbee, Arthur D.; Masuda, Jason Douglas, 1977- (International Union of Crystallography, 2017-04-21)
The title compound, C26H38ClN2OP, was synthesized by reacting phosphoryl chloride with N,N′-bis(2,6-diisopropylphenyl)ethane-1,2-diamine in the presence of N-methylmorpholine which acted as an auxilliary base to quench the HCl released as a by-product. The resultant N-heterocyclic phosphine five-membered ring adopts a half-chair conformation and features a tetracoordinate P atom ligated by the chelating diamine [P—N = 1.6348 (14) and 1.6192 (14) Å], one double-bonded O atom [P1—O1 = 1.4652 (12) Å] and one Cl atom [P1—Cl1 = 2.0592 (7) Å]. The sterically hindered 2,6-diisopropylphenyl (Dipp) groups twist away from the central heterocycle, with torsion angles of −75.66 (19) and 83.39 (19)° for the P—N—Car—Car links. A number of intramolecular C—H...N, C—H...O and C—H...Cl close contacts occur. In the crystal, molecules are linked by C—H...O hydrogen bonds to generate [010] chains. C—H...Π interactions are also observed....
Reaction of sterically encumbered phenols, TEMPO-H, and organocarbonyl insertion reactions with L-AlH[subscript2] (L = HC(MeCNDipp)[subscript2], Dipp = 2,6- diisopropylphenyl)

Keyes, Lauren K.; Todd, Angela D. K.; Giffin, Nick A.; Veinot, Alex J.; Hendsbee, Arthur D.; Robertson, Katherine N.; Geier, Stephen J.; Masuda, Jason Douglas, 1977- (Royal Society of Chemistry, 2017-07-26)
<The reaction of L-AlH2 (L = HC(MeCNDipp)2, Dipp = 2,6-diisopropylphenyl) with sterically bulky phenols (2,4,6-trimethylphenol, MesOH; 2,6-diisopropylphenol, DippOH) and an N-hydroxylamine (1-hydroxy-2,2,6,6-tetramethyl-piperidine, TEMPO-H) forms an Al–O bond with concomitant loss of hydrogen gas to give L-Al(H)OMes, L-Al(H)ODipp and L-Al(H)TEMPO, respectively. Reaction with 1 or 2 equivalents of benzaldehyde or 1 equivalent of benzophenone results in insertion of carbonyl into the Al–H bond(s) to give the related benzylate and diphenylmethoxide products. Compounds L-Al(H)OMes, L-Al(H)ODipp, L-Al(H)TEMPO, L-Al(H)OBn, L-Al(OBn)2, and L-Al(H)OCHPh2 have been characterized by NMR spectroscopy, elemental analysis, infrared spectroscopy and single crystal X-ray diffraction. The reaction of L-Al(H)OBn with pinacol borane gives a complex mixture of unidentifiable products, providing evidence of the importance of the triflate group in the known aldehyde and ketone hydroboration catalyst L-Al(H)OTf (OTf = CF3SO3−)....