dc.creator |
Piorko, Adam |
|
dc.creator |
Christie, Sean |
|
dc.creator |
Zaworotko, Michael J. |
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dc.date.accessioned |
2013-06-14T14:41:23Z |
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dc.date.available |
2013-06-14T14:41:23Z |
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dc.date.issued |
1995-01 |
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dc.identifier.issn |
0108-2701 |
|
dc.identifier.uri |
http://library2.smu.ca/xmlui/handle/01/24995 |
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dc.description |
Publisher's version/PDF |
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dc.description.abstract |
The structures of ([eta superscript 5]-cyclopentadienyl)[(1,2,3,4,4a,10a-[eta superscript 6])-dibenzo[b,e][1,4]dioxin]iron(II) hexafluorophosphate (1), [Fe(C[subscript 5]H[subscript 5])(C[subscript 12]H[subscript 8]O[subscript 2])]PF[subscript 6], and ([eta superscript 5]-cyclopentadienyl)[(1,2,3,4,4a,10a-[eta superscript 6])-1-methyldibenzo[b,e][1,4]dioxin]iron(II) hexafluorophosphate Et[subscript 2]O solvate (2), [Fe(C[subscript 5]H[subscript 5])(C[subscript 13]H[subscript 10]O[subscript 2])]PF[subscript 6].0.5C[subscript 4]H[subscript 10]O, were detd. The dihedral angle between the outer rings of dibenzodioxin is 175.8(2) in (1) and 177.55(19)° in (2). The planes of the coordinated arene and cyclopentadienyl (Cp) rings are nearly parallel for both complexes. The Fe atom is centered above the Cp ring while Fe-C distances involving the quaternary C atoms of the coordinated arene rings are slightly longer than those involving the other aromatic C atoms, particularly for complex (2). In the central dioxin ring of both complexes, O-C bonds of the coordinated ring are shorter than those of the uncoordinated ring. |
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dc.description.provenance |
Submitted by Trish Grelot (trish.grelot@smu.ca) on 2013-06-14T14:41:23Z
No. of bitstreams: 1
piorko_adam_article_1995_k.pdf: 436213 bytes, checksum: f34487f425f35457fd5a4136076d1bdb (MD5) |
en |
dc.description.provenance |
Made available in DSpace on 2013-06-14T14:41:23Z (GMT). No. of bitstreams: 1
piorko_adam_article_1995_k.pdf: 436213 bytes, checksum: f34487f425f35457fd5a4136076d1bdb (MD5)
Previous issue date: 1995 |
en |
dc.language.iso |
en |
en_CA |
dc.publisher |
International Union of Crystallography |
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dc.relation.uri |
http://dx.doi.org/10.1107/S010827019400363X |
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dc.subject.lcsh |
Organometallic compounds |
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dc.subject.lcsh |
Crystallography |
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dc.subject.lcsh |
Metal complexes |
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dc.subject.lcsh |
Iron salts |
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dc.title |
Hexafluorophosphate salts of cyclopentadienyliron(II) complexes of dibenzodioxin and 1-methyldibenzodioxin |
en_CA |
dc.type |
Text |
en_CA |
dcterms.bibliographicCitation |
Acta Crystallographica C51, 26-29. (1995) |
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