1,3-Bis(2,6-diisopropylphenyl)-2-trichloromethylimidazolidine

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dc.creator Stack, Darcie L.
dc.creator Masuda, Jason Douglas, 1977-
dc.date.accessioned 2021-08-16T10:42:07Z
dc.date.available 2021-08-16T10:42:07Z
dc.date.issued 2017-10-12
dc.identifier.issn 1422-8599
dc.identifier.uri http://library2.smu.ca/xmlui/handle/01/29788
dc.description Published Version en_CA
dc.description.abstract A new chloroform adduct of the N-heterocyclic carbene (NHC) 1,3-bis(2,6-diisopropylphenyl)imidazolidin-2-ylidene (SIPr) has been prepared via C&ndash;H bond activation of the chloroform at the carbene carbon. This redox product was crystallized and was characterized by <sup>1</sup>H and <sup>13</sup>C-NMR spectroscopy, elemental analysis (EA), and single-crystal X-ray diffraction. The <sup>1</sup>H and <sup>13</sup>C-NMR spectroscopic data are in agreement with the crystal structure. Density functional theory (DFT) calculations were performed as a means for comparison to experimental data and the computational results are in agreement with those obtained experimentally. en_CA
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dc.language.iso en en_CA
dc.publisher MDPI en_CA
dc.rights This is an open access article distributed under the  Creative Commons Attribution License which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.
dc.subject.lcsh Chloroform
dc.subject.lcsh Heterocyclic compounds
dc.subject.lcsh Carbenes (Methylene compounds)
dc.title 1,3-Bis(2,6-diisopropylphenyl)-2-trichloromethylimidazolidine en_CA
dc.type Text en_CA
dcterms.bibliographicCitation Molbank 2017(4), M962. (2017) en_CA
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This is an open access article distributed under the  Creative Commons Attribution License which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.
 
 

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